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June

2024IESPaper:

ET37Howpropermeasurementoflo carbon ydogen’scarbon

intensity

can

re ucere lat ry

riskAlexBarnes,VisitingResearchFellow,

OIESThecontentsofthispaperaretheauthor’ssoleresponsibility.TheydonotnecessarilyrepresenttheviewsoftheOxfordInstituteforEnergyStudiesoranyofitsmembers.1Thecontentsofthispaerretheuthor’solresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

yCopyright?2024OxfordInstituteforEnergy

Studies(RegisteredCharity,No.

286084)Thispublicationmaybereproducedinpartforeducationalornon-profitpurposeswithoutspecialpermissionfromthecopyrightholder,providedacknowledgementofthesourceismade.NouseofthispublicationmaybemadeforresaleorforanyothercommercialpurposewhatsoeverwithoutpriorpermissioninwritingfromtheOxfordInstituteforEnergy

Studies.ISBN978-1-

8467-247-8ummaryHy

rogen

wi a

lo c

bo

inte ity

(‘lowrbonhydogen’)1

is

a eansof

debon

inge s

ofprou

d

v

ele

l

isalso

see

s

a

ytoring

va

able n a ele

tricityindosoar,andher

bv

c

min eofass tedithnt

rmitteenrated

yr

ne

ab e

ctty

ene

tio Ke

s esforpicmak

rsost

f

lo ca

on drog anditsc

rbon

int sity.Botharyonsidralyde

endenttheconmywhicarenotesilyelectfied.Hydrgeoftharonrolmth

highe

rodtiophwysuse

.Theividigline

betweerogen

as

a eans

of

de rboniatiois

notcle cut

T h logi

sconsi e

uncel

ctrificativolvinywh

hanlowarbonhnd r remaect .Elctr

lyticrogenisale

shydr

ge illeusedbec

use

f

h

c

ver. nc

rns atlw

arnhyrog

nrenablgd

plotha

gov

r esneedtotheowescost($/kg

2sno ntjusthatebutlso

t

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arac

ievi

g

t

b

twhihwlde

enon

the

d

set

nty bo owmchf

cie

t

e

f

el

tricityay s r reorceme

nenlwcarhydroeatesttmofredutioofthey

rogenaellas

eem

sions

(tC bated/k

H2h

dro

en’s

l carbon

i

tensi

.

Pr

uceeedtkn

wt

at

they mplywith

gov

r t ii

onsalowest

ost.cu

e n enlatebased

n

ol rorb

ad

term cas‘clean’rrenwblarinade

uatetheydonotgivanyindicatnofthecarbonint

nsitoftheh

droge,whichiste

key eic

fromof w

arbo

hydr en,whilstusersneedoshowheyareeducingemissions,andhathearedoingthTaatecaocompaa

ioneitheoideer ecte

Deendefiiti

ns

wi re cabon

ccou

i anitidifiultthforcost

of ehydrgen($/kg2)nalikeforlikebasis,ortereliecostofydr

g (tCO2aba

d/kgH2)bointen

ty

depe sontheeissioninludeinthealculation(sys

me

issionsCalculatiboundarycal

ulatinh rogen cndcope)anthisdiffth miss

ncl edsbetweestre

mjurisdicti s.

The

e ealso

diff

r t thodologisforissnin

ude

t p uionofayfedscks(.goil,natural

gaiomassnludingioascol)ad

socesg

nd

tra pttiontthehydr

genp uction

pl . st m

emis ns

wie d

o

t tpe

of

f ds ,

he ethdn

efficiencyof

pr

duc

n,

a

the

dis ce,

met

o

nd

e

i

e

y

trrtation thhydroen

roductionplnt.Thecaron

i

te ityof

fee

stocks liklytobevrysourcespecifi

.Emi insfomhydrgenproductinwlbeetermedbythepr

duct

n

proc susedanthe

energyusedntht

prs

ad based

te nogshavediferentprductonffic

ncies,e

k de

ermin tofelectl

ic

h rogen’s

c

rb itensityis

thecostcarb

idc

rbonsityss.Elerolystre

rates.fthee

ctricis

d. enwablelectc

y

is ro

emissio

s

b

t

its

int

rmittencygher

L el

edost Hdrge(LCO)dutol

w

r

el troly r

l f tr.

Howeverinte ityof

grielerityvaries

onsider

bly weencountriesbsedn

theenerationresltsnthemiEle

tricithas b

baland

in

eal

t

me

i.e.

h

a

ount

f

electri

it

generat

d

and

upplied

o

thegri

mustul

t

e ountta

e

fro theriatn

givem

nt ainin

s

ste talityT

us,the rbsae

timnt sitofhhydrr

gen

sin ri

ele ity

e snthpro

u

io

.

di

onal

d and

fro

trbointlysers

caemis

ons itesults

inorefossilfelgeneraonbeinusebutelectroly

ersityotgridthereltighrridanhpalanc

thegridbyusing‘surplus’renewableelectricitywhichmightotherwisebe

curtailed.Te oral

c

rrel

ion

eas

res carboofhydoge

based

on e

el tricity

use nag

entime

peri

d

e.g

hal

hou

ho

, ontmreensitc

ur

tely ttheo

hydrog

n

b

dntenitarArealera

dre r

men

at

lec

it

r

s

lanc,a

d

t t

tdu drt ti

e

riodrbt timeonth

carb

nin

nsity

o

eel

ricithydrog rodu

ti . se

oflo er

or

la nrulesnheEU,

uchmo

th

cor

atir

s

ste

a

eraging,

s

lts

in

ro

nprodu

tion

with rboitenitiewhi

hanbeigherthanhihcarb

n

hydrog orfosfuels.

ItInthispaperlowcarbonhydrogenisdefinedashydrogenwithasignificantlylowercarbonintensitythanhydrogenbasedonfossilfuelswithoutCCS.SimilarlylowcarbonelectricityisdefinedaselectricitysignificantlylowercarbonintensitythanelectricitybasedonfossilfuelswithoutCCS.Lowcarbonelectricitythereforeincludesrenewables(e.g.wind,solar,hydro,geothermal,biomass),nuclearandfossilfuelgenerationwith

CCS.2Thecontentsofthispaerretheuthor’solresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

ygri

a hydr encarbo

int

nsitie meet

E rqui

ementscou

ries

with uchighhosecoutriewhic

haver w ron

ntesiti .heeffe

tgniedyhge

ingllowsEalongefect

oectro erefficncy.

Ta

t i

en

el trolseriSw

d

n i

g

gr ele

tr

i till

asa

lo

r

ydro

n

c

r

on

inte ityohecuntr

es

e ep

Fr c.

Th

h rtea

on

int sityof

el

ct ytic droentday

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t

e ostffientele

tr

lysers ig id tricity

i l

theorezeroar

oelctritywl

e

ee d

in

f rtoremveemiinsinfutur

if

negati emi iosarerequ

red

to main

wit

in cbonbug

t.Theimatofdifferettmporacorrelioneriodsvariescon

id

ably eon

theloo

ng

a

t

e

im

ct

f

ourly,

eekly

an

nnual

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re

tion

o

grid

in

t

e

w

teelectric

y yem

fo

n l

os rre

tio resuld

n

hig mis

o

s ut

theid.AUS

study2intrnetionCHas

notnece

y

pr

po

onat

y

hi

h

.

Allow

ng

eract

b

t

e

ereslt

in

lo

er

idctroly

e rectad

th ricanpact

o

ydro

n

p

je

t

d ignand o i ,

aissi

s,

as

hown

by studp er

s to

emiss

n sn atholycorlionrlts

ne tr

cit ta.3

Usi e

study’sareatrrdutionin

missionsoem

sionsved. igdta

rlokinattestoric e

mi eL

Oa t y

ono opti

i low

ca4ish ner

y

par ig r

L

OH are

uof r t i

v

t

nta

low LCO perkof

eission

r ctionoparedoonly

usinhydrogenneableanish

griddat tanbsand owrpro

u

tion tgeneratiohselectricity.Low

carbodrogen

faces

hig r

gulatorubs

es rtar

ettat

is

g value

fny

insk

becaus–

t

pportrsfred

citisentireldepnentongvernmnt

tbsinessase.thefrenedstogmissnsroprccountinofcar

ninte

ention

w

hedemons

atintnsit

usiuy

co

elati

n

f

he

us

r

rd

ferent

rule ve misle ngpiure

ofthe e stoemiss

nscti

an

h

nc

n

e

d

ais

lloc

tio

f

e ces.

A

hig

er

L

Hdos t

ne sarilymenahighostofem

sioncn

alsottriegrionbteenleco

seranr cin.

Str

ter poalcrrleri,wichcaresulti

alwin idemis

i s.It

c

ul lsoessn

theefo ti

l

y

equ

m

sinc tive

to

en e a

an

grid ctr

ityey e

i

lo crbon

intensitL

O andsletrol

serictt

mporalenabere ctiwill

havecor

elatiules

i

ed

wit li

ing

sca supr

bas nhearboninte

sitof

lo arb

nhydroe,nabl

a

si lifi

atio fthe le h

hr cesrgutor

uncintyforroctsboth

intermsof

u

derst ing

the

curre rle andheri offutu rulecha

ges.Propercomarionoflowcarbonh

drog

n oduc

d

in iffeet

countrs

requirescom

onmetho

ology

fo

s

r

g

missi

s

lon

t

e

v

lue

ai

,

an

a mmonme la e

b e

onIPHE etodolgforD

trinin

the

Gre usGa

Em

si s

ssociatcarb

inten

ity

o

v

id

th

confu

io

over

er

s.

h

om

on

thodolo

oul

b

ba

ed

on

ewith

he od tio

ofHydrgnThiswldstillbleoiestoseteirwncarbointensitytresold,thelevelofsupporttorovieandhotoproide

it.Theeasond’etroraronhydroesattwillassistormetsnhireffortsecarnietheeconoies.Thisntuependsonthcotffectenesoflwcarbonhrogenioings.Iflowarbodgfidontrteiriskslosigtgvemntpponees

fco

p

nies

o

est

n

he

c

r,

major

o

rce

f

e

ul

to

i

.

rkets

re

t

l

ce

a

an

ingbltcanesextraties

sthsesksto

d witc tf

owarbon

hydro

en

p

vidi

g

able

lear

e

ul

tor

r

me

ork

Cr

i

lly

h

nclbeintralie

fin al

costs, oj t

i

ple tio btr

lesss

GHG

e s

ion G

vern nts

ca nable

mar

e o

b gow

theesproeraccountingflowarbonhdrogen’scrniteny,alonsicmmonccountigsndardsandnmnclatur.Onlyriorsaccuntigstads,bkeupyflxiblgvernmetsuportbasdcarbiteny,illeableestentinlocaonyonsly,infrastrucureanddemadhereitakesthmtsens-bothfinacllyndenronmenta

y.Ricks,Xu,Jenkins(2023)‘Minimizingemissionsfromgrid-basedhydrogenproductionintheUnitedStates.’EnvironmentalResearchLetters.WilsonRicksetal2023Environ.Res.Lett.18

0140253Ruhnau,Schiele(2023)‘Flexiblegreenhydrogen:Theeffectofrelaxingsimultaneityrequirementsonprojectdesign,economics,andpowersectoremissions.’Energy

Policy.4Sorrenti,Zheng,Singlitico,You(2023)‘Low-carbonandcost-efficienthydrogenoptimisationthroughagridconnectedelectrolyser:ThecaseofGreenLabSkive.’RenewableandSustainableEnergy

Reviews.3Thecontentsofthispaerretheuthor’solresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

yontentsSummary

iiContents

vFigures

vTables

v1. Introduction

12. Challengesforstakeholders

12.1Policymakers

2.2Hydrogenproducers

2.3Hydrogenusers

3. Clarifyingthenomenclature83.1Thecolourof

hydrogen3.2Clean,renewableorlowcarbonhydrogen

4. Measuringhydrogen’scarbonintensity

114.1SystemBoundaryandScopeEmissions.

114.2Emissionscalculationmethodology

134.3Measuringupstreamemissions

134.4Measuringhydrogenproductionemissions

14Measuringthecarbonintensityofelectricityusedinelectrolysis.

14Temporalcorrelation,additionalityandgeographiccorrelation175.2Comparinghourlyandmonthlytemporalcorrelation175.3Comparinghourlycorrelationwithaveragesystem

matching19Interactionofelectrolyserefficiencywithtemporalcorrelation

20Impactofloosertemporalcorrelationrulesonfuturerenewableenergyneeds235.6Comparinghourly,weeklyandannualtemporalcorrelation245.7Interactionwiththegrid

286.Reducingregulatoryriskforlowcarbonhydrogen317.Conclusions

35FiguresFigure1:Wrngtemp

ratures

f selectedrenewableheattechnologiesand

temperaturerequirmntofsectedindustris

3Figure2:Esti

ation

of newableelectricitygenerationneededfor1MWhbyenergyservicesandbtransf ationpatha

..

...

...Figure3:Illutrationoftrade-offsbetweenusinglowcarbonhydrogenorothertechnologies

todecarose

..

...

..

5Figure4:IllustrationofsystemboundaryandScopeEmissionsforhydrogen

1Figure5:EU27andUKGridElectricityCarbonFootprint2021

5Figure6:ComparisonofEU27andUKgenerationmixandelectricitygridcarbonintensity

5Figur

7: omparon

of

EU andUK2021gridelectricityandelectrolytichydrogencarbonintensibased monthlycor

el

tion

Figure

8: omarisoofU27ad

UK

2 1electrolytichydrogencarbonintensitybasedon

monthcorrelFigurecarboi and

fossil carbninenty..

...

9:Comprisonofcaronelectrlyserrunnghoursundersystemmatchingand

hydrogeniensityusinhurlyteporalcorretion...

...

04Thecontentsofthispaerretheuthor’solresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

yigure10:Impactofelectrolyserefficiencyonhydrogencarbonintensitybyselectedcountry

1Figure11:Additionalcarbonintensitybycountryandelectrolyserefficiency

2Figure12:ZerocarbonelectricityrequiredtoensurecarbonneutralhydrogenusingDAC

4Figure13:GridbasedhydrogenemissionsunderdifferentscenariosinWesternUS

6Figure14:LCOHofgridbasedhydrogenunderdifferentscenariosinWesternUS

7Figure16:GreenLabSkiveCO2abatementcostsscenarios

15Thecontentsofthispaerretheuthor’solresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

yTablesTable1:Carbonintensityofdifferenthydrogenproductionpathways

2Table2:Comparisonofdifferenthydrogendefinitions

9Table3:Electrolyserefficiencyratesandelectricityconsumptionperunitofhydrogenproduced

1Table4:LCOHandimpactonpowersectoremissionsunderdifferentscenariosinGermany

9Table5:ComparisonofLCOHandemissionsreductionsunderdifferentscenariosinGermany9Table6:ComparingHydrogenCarbonIntensityandLCOHscenariosforGreenLabSkive

01.

IntroductionInrecentyearstherehasbeenanincreasingfocusontheuseofhydrogenwithalowcarbonintensity(‘low

carbon

hydrogen’)

as

a

means

of

decarbonising

sectors

of

the

economy

which

are

not

easilyelectrifie Hydrogepoducdviaectrysis

islr,andthr

boringvaablereneableroblmsssciatd

withelectricity neratedintermittetenea

ehydrogn

iwindolct

cil fininenratiprces

,lsoseenaecomi

g.

T

e isalreadinhe nufac

uawy

feo

tifafch

micydr

ge

mar

t

ereand

fe

ti rs.

H ev

rihcarboint

ntyadthrefe

not

sui leas

ausdinthl ish

da

bonisith vd y.5

Issentilodi

eiatbetenxti

gvirtuallmeashig

cni

tensityipdueddoect

fydr ec

rbons re

oregen.

Thcaoi

tnsty

ofl arbonh

drogennprodctionpathayndthenputsue

.can

lso

va considrablydeLowc

rbon

hydr ensa

mandlond

gns(buty

o(G )

emi

io

s.

Lo

c

r

nso

gonment

inerv tnos

men a ansnotte

o

ly ean to

r ueGreenoseGass e

exp iisuired

tmetgdcaronistion

tan

t s

l e t nenddnco

ra o nd tusahs comp

e ith

opae,wayofist

gfosilfu

lsndother e s

ofant

on rehtweri

iss.Locaroydrognherforarbnisao.Governntswill

temsco-effeivde

rnisa

it

e s

of

ydrog ,

blsois

carbolow r

o

h roew

l

r uoldothiif

they

kn ot

onlofi

sio

s

re

cti

n

for

ac

kh

drogen.

e

am

ppliesie

sit

andocomp

niewho

maed,of

th

c

my. canen theostbecnsidering

inglowc

rb

hyd

g

.tatlowcarbn

hydro

en subject

to

f

go r ent

s po

t)

an ncrtai

tyTherequimetforpottiallyhighle(e.g.confsingor

difrnmentspptornterventmeanofreulatyisk(.gchangesineelsrntrulesidiffrentjurisdictin).

Thiper

exami sthecalleges

facingstakeholders

with

regards

to

understanding

hydrogen’s

carbon

intensity;

the

confusing

nomenclatureappied

tcanharisk

canlo

carbon dro n;ntheim

act

th differen pro

ches

to easuncarbnintensityydrog costs

an

its

act

al

car

on

i

tensity.

t

then

prop

s

s

ways

in hichr

gulatoryr

duced.2.Challengesfor

stakeholdersGovernmhyrogebeeasilyal

ngsidt prducrs

nd

sers lhaveaninterst

nclea

ro

it bility

oointe

siulatoryfraeworkcrbiseseooflowcaron

hrlowarbonwiccnnotogni

keAsecefololtrifdwhoitscostreativ

tocarbydroenestabonlectricitythethothrdecarbo

satnsoluonsanduren

unabatd

fossilf l

se.Policy

makersPolicymakersfacetwokeychallengesconcerninglowcarbon

hydrogen:Ithighcotcomparedtocurrenthydrogenproductionandcomparedtothefossilfuelsitaimsto

epl e.Itscarbonintensityandhenceitsabilitytocontributetodecarbonisation

targets.low

c onhdognde

endingTheIEA

reporranofosfloc on.as

d021

ceAfuels

(nral sor ngcl

guot

s

a neof.0sifi

at )

with.0S

/k1.to

3.6nproductioohydg

n/kgfor

fpathaandas

d

o

ssililful

asedhydrgenwit

C,and3.–2UD/kg

forel trolysiusing

loeisonelecticit

.6Decarbonisingexistinghydrogenuseshouldbearelativelyeasypolicygoalasdemandforthehydrogenalreadyexists,andthereforedoesnotrequirethesamedegreeofchangeascompanieswhichwillneedtoswitchfromfossilfuelsto

hydrogen.6IEA(2023),GlobalHydrogenReview2023,IEA,Paris,Licence:CCBY4.0.Pages88to

89.1Thecontentsofthispaerretheuthors’olresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

yheresaloawib

low

a

n deofnatralas,

corangeocarbonntrea

issi

sornuclerfuels.

Bnsitiesfordiffenthdrognssciedith

np

s

u aed

on

IE

figu

es7

th

se

erouctionpatwas.Thefiguresheroduinnrnrtatinumarisedintheable

below:Table1:Carbonintensityofdifferenthydrogenproduction

pathwaysRangeofcarbonintensity

(kgCO2e/kgH2SteamMethaneReformingwithout

CCS10–

13Coalgasificationwithout

CCS22-26SteamMethaneReformingwith

CCS*1.5–

6.2Coalgasificationwith

CCS*2.6–

6.3Electrolysisfromgrid-based

electricity0.5*–

24.0***Nuclear

electricity0.1–

0.3*Assumes93%capture

rate**BasedonSwedishgridcarbonintensityof10g

CO2e/kWh.***Basedonglobalaveragecarbonintensityof460gCO2e/kWh.Ingridswithcarbonintensityabovetheglobalaveragethecarbonintensityofhydrogenwillbe

higher.enti

ns

o

support

low

c

rb

n

hydro

en

nclud andatytrgetssuchasthe

EUGovernmeninterequirementthat(Renewable

Fue2 o droge us

d

i i

dustryof oBiological

Origi

- FNBOs,

t03 s

based rene

abl ectrityUKusidiesfor‘lowcarbon

hydrogen’undertheHydrogenProductionBusinessModel,ortheUS45Vtaxcreditsfor‘cleanhydrogen’undertheInflationReduction

Act.Theividi

glinebetwee

el

ctrificati anlow

arbon

h rogen

as

a eans

of

de rboniatiois

notlogirolvinndhrremscnsirbeunctntyabouthowmchsendyhichectrs.IRNAnotsthata‘rangeofoptionstoproducehighiactcit

(wit

resista e,infrred,iduction,microwve

ancle cut

T hhydrgenwlbetemp

at

e

aexists

a

d y

bdiffer tedu

em

e

ener

efficient

han

he

burning

of

green

hydrogen’.8

Fi

repplictionsandtheirheatrequirementscomparedtodiffernt

soulasmheating)b

o mp

ess

of ergy.Ibid.8IRENA(2022)Greenhydrogenforindustry.Aguidetopolicymaking.Page

12.2Thecontentsofthispaerretheuthors’olresposibility.yotecessarilrepresenttheviewsit

Members.ofthOorInstitutfornergyStudieora

yFigure1:Workingtemperaturesforselectedrenewableheattechnologiesandtemperaturerequirementofselected

industriesSource:IRENA(2022),Greenhydrogenforindustry:Aguidetopolicymaking,InternationalRenewablenergyAgency,AbuDhabi.Figure1.3Workingtemperaturesforselectedrenewableheattechnologiesandtemperaturerequirementofselected

industries.Hydrogenialsnasameansstorinsulusreneableeletricituilitisrequred.Oviouscompetitsortisluumpydro9nbaties,wherutilityorsoldca.OtherpotntialcoptitiludthrmaloragAllhecetgthnolishavtadva

tagest

lac o de

n

d nce

whichand

isa

va

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