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1、 231Vol.23No.1 20111CORROSION SCIENCE AND PROTECTION TECHNOLOGY Jan.20111,1,1,21.,266100;2.,110015:,.:;:TG172.5:A:10026495(201101009306Research Progress on Corrosion of Carbon Steels Under Rust Layerin Marine EnvironmentZHENG Ying-ying1,ZOU Yan1,WANG Jia1,21.College of Chemistry and Chemical Enginee
2、ring,Ocean University of China,Qingdao266100;2.State Key Laboratory for Corrosion and Protection,Shenyang110015Abstract:Resaerch activities and progress on corrosion of carbon steel covered with rust layerin recent years were summarized,in particular,on the physicochemical properties of the rust,the
3、electrochemical characteristics of corrosion of steels beneath rust layer and the relations betweenrust and evolution of corrosion process Several inuencing factors on corrosion behavior of steelswere analyzed,and the trends of research in thiseld were also postulatedKey words:carbon steel;corrosion
4、 behavior;rust layer;marine environment,.,.,.,.,.94231:9596231:9798 13 23 : (1 , . , . (2 , , , . (3 , , . , , . , . 1 Melchers R E. Eect on marine immersion corrosion of carbon content of low alloy steels J. Corros. Sci., 2003, 45(11: 2609. 2 Melchers R E, Jerey R. Early corrosion of mild steel in
5、seawater J. Corros. Sci., 2005, 47 (7: 1678. 3 Pineau S, Sabot R, Quillet L. Formation of the Fe(IIIII hydroxysulphate green rust during marine corrosion of steel associated to molecular detection of dissimilatory sulphite-reductaseJ. Corros. Sci., 2008, 50(4: 1099. 4 Evans U R, Taylor C A J. Mechan
6、ism of atmospheric rusting J. Corros. Sci. 1972, 12(3: 227. 5 Stratmann M, Bohnenkamp K, Engell H J. An electrochemical study of phase - transition in rust layers J. Corros. Sci., 1983, 23(9: 969. 6 Ma Y T, Li Y, Wang F H. The eect of -FeOOH on the corrosion behavior of low carbon steel exposed in t
7、ropic marine environmentJ. Mater. Chem. Phys., 2008, 112(3: 844. 7 14 15 16 18 17 19 20 21 22 23 24 25 26 . J. , 2001, 13(2: 81 J. 8 , . , 2000, 12(6: 315. 9 , , . J. , 2002, (4: 14. , . 10 , J. , 2007, 27(6: 321 11 Dillmann Ph, Mazaudier F, Hoerl S. Advances in undere standing atmospheric corrosion
8、 of iron. I. Rust characterisation of ancient ferrous artefacts exposed to indoor atmospheric corrosion J. Corros. Sci., 2004, 46(6: 1401. 12 Deliyanni E A, Bakoyannakis D N, Zouboulis A I, et al. Akaganite-type -FeO(OH nanocrystals: preparation e 27 28 29 30 31 and characterizationJ. Microporous Me
9、soporous Mater., 2001, 42(1: 49. Ohtsuka T, Komatsu T. Enhancement of electric conductivity of the rust layer by adsorption of water J. Corros. Sci., 2005, 47(10: 2571. Hoerl S, Mazaudier F, Dillmann Ph, et al. Advances e in understanding atmospheric corrosion of iron.II. Mechanistic modelling of we
10、t-dry cycles J. Corros. Sci., 2004, 46(6: 1431. Qu D Y. Application of a.c. impedance technique to the study of the proton diusion process in the porous MnO2 electrode J. Electrochim. Acta, 2003, 48 (12: 1675. Memet J B, Girault P, Sabot R, et al. Electrochemical impedance spectroscopy of a free-sta
11、nding oxide lm J. Electrochim. Acta, 2002, 47(7: 1043. , , . J , 2006, 18(4: 269. , , . J. , 2001, 37(02: 193. Lair V, Antony H, Legrand L, et al. Electrochemical reduction of ferric corrosion products and evaluation of galvanic coupling with iron J. Corros. Sci, 2006, 48(8: 2050. Nishimura T, Katay
12、ama H, Noda K. Electrochemical behavior of rust formed on carbon steel in a wet/dry environment containing chloride ionsJ. Corrosion, 2000, 56(9: 935. . M. : , 1989: 164. Allam I M, Arlow J S, Saricimen H. Initial stages of atmospheric corrosion of steel in the Arabian GulfJ. Corros. Sci., 1991, 32(
13、4: 417. , , . J. , 2006, 28(4: 6. Melchers R E. Eect of small compositional changes on marine immersion corrosion of low alloy steels J. Corros. Sci., 2004, 46(7: 1669. , , . 3 J. , 2002, 23(7: 288. Refait Ph, Memet J B, Bon C, et al. Formation of the Fe(II-Fe(III hydroxysulphate green rust during m
14、arine corrosion of steelJ. Corros. Sci., 2003, 45(4: 833. Ona-Nguema G, Abdelmoula M, Jorand F, et al. Iron (II, III hydroxycarbonate green rust formation and stabilization from lepidocrocite bioreductionJ. Environ. Sci. Technol., 2002, 36(1, 16. , , . J. , 2007, 28(1: 17. . M. : , 1984: 230. Liu H, Wei Y, Sun Y H. The formation mechanism from ferrihydrite to hematite when Fe (II used as a catalyst J. J. Mol.
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