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1、 南京工程學院 nanjing institute of technology畢業(yè)設計英文資料翻譯 translation of the english material of graduation design學生姓名: 學 號 : 240112608 name: chen jianwei number: 240112608 班 級: k 暖通 111 class: k-nuantong111 所在學院: 康尼學院 college: kangni college 專 業(yè): 建筑環(huán)境與設備工程 profession: building environment and equipment eng
2、ineering 指導教師: tutor: liu minghui 2015年 3月 7日 chapter 1thermodynamics and refrigeration cycles thermodynamics . 1.1 first law of thermodynamics . 1.2 second law of thermodynamics . 1.2 thermodynamic analysis of refrigeration cycles . 1.3 equations of state . 1.3 calculating thermodynamic properties
3、. 1.4 compression refrigeration cycles . 1.6 carnot cycle . 1.6 theoretical single-stage cycle using a pure refrigerant or azeotropic mixture . 1.8 lorenz refrigeration cycle . 1.9 theoretical single-stage cycle using zeotropic refrigerant mixture . 1.10 multistage vapor compression refrigeration cy
4、cles . 1.10 actual refrigeration systems . 1.12 absorption refrigeration cycles . 1.14 ideal thermal cycle . 1.14 working fluid phase changeconstraints . 1.14 working fluids . 1.15 absorption cycle representations . 1.16 conceptualizing the cycle . 1.16 absorption cycle modeling . 1.17 ammonia-water
5、 absorption cycles . 1.19 nomenclature for examples . 1.20thermodynamics is the study of energy, its transformations, and its relation to states of matter. this chapter covers the application of thermodynamics to refrigeration cycles. the first part reviews the first and second laws of thermodynamic
6、s and presents methods for calculating thermodynamic properties. the second and third parts address compression and absorption refrigeration cycles, two common methods of thermal energy transfer.thermodynamicsa thermodynamic system is a region in space or a quantity of matter bounded by a closed sur
7、face. the surroundings include everything external to the system, and the system is separated fromthe surroundings by the system boundaries. these boundaries can be movable or fixed, real or imaginary. entropy and energy are important in any thermodynamic system. entropy measures the molecular disor
8、der of a system. the more mixed a system, the greater its entropy; an orderly or unmixed configuration is one of low entropy. energy has the capacity for producing an effect and can be categorized into either stored or transient forms.stored energythermal (internal) energy is caused by the motion of
9、 molecules and/or intermolecular forces.potential energy (pe) is caused by attractive forces existing between molecules, or the elevation of the system. (1)wherem =massg = local acceleration of gravityz = elevation above horizontal reference planekinetic energy (ke) is the energy caused by the veloc
10、ity of molecules and is expressed as (2)where v is the velocity of a fluid stream crossing the system boundary.chemical energy is caused by the arrangement of atoms composing the molecules.nuclear (atomic) energy derives from the cohesive forces holding protons and neutrons together as the atoms nuc
11、leus.energy in transitionheat q is the mechanism that transfers energy across the boundaries of systems with differing temperatures, always toward the lower temperature. heat is positive when energy is added to the system (see figure 1).work is the mechanism that transfers energy across the boundari
12、es of systems with differing pressures (or force of any kind),always toward the lower pressure. if the total effect produced in the system can be reduced to the raising of a weight, then nothing but work has crossed the boundary. work is positive when energy is removed from the system (see figure 1)
13、.mechanical or shaft work w is the energy delivered or absorbed by a mechanism, such as a turbine, air compressor, or internal combustion engine.flow work is energy carried into or transmitted across the system boundary because a pumping process occurs somewhere outside the system, causing fluid to
14、enter the system. it can bemore easily understood as the work done by the fluid just outside the system on the adjacent fluid entering the system to force or push it into the system. flow work also occurs as fluid leaves thesystem.flow work =pv (3)where p is the pressure and v is the specific volume
15、, or the volume displaced per unit mass evaluated at the inlet or exit.a property of a system is any observable characteristic of the system. the state of a system is defined by specifying the minimum set of independent properties. the most common thermodynamic properties are temperature t, pressure
16、 p, and specific volume v or density . additional thermodynamic properties include entropy, stored forms of energy, and enthalpy.frequently, thermodynamic properties combine to form other properties. enthalpy h is an important property that includes internal energy and flow work and is defined as (4
17、)where u is the internal energy per unit mass.each property in a given state has only one definite value, and any property always has the same value for a given state, regardless of how the substance arrived at that state.a process is a change in state that can be defined as any change in the proper
18、ties of a system. a process is described by specifying the initial and final equilibrium states, the path (if identifiable), and the interactions that take place across system boundaries during theprocess.a cycle is a process or a series of processes wherein the initial and final states of the syste
19、m are identical. therefore, at the conclusion of a cycle, all the properties have the same value they had at the beginning. refrigerant circulating in a closed system undergoes acycle.a pure substance has a homogeneous and invariable chemical composition. it can exist in more than one phase, but the
20、 chemical composition is the same in all phases.if a substance is liquid at the saturation temperature and pressure,it is called a saturated liquid. if the temperature of the liquid is lower than the saturation temperature for the existing pressure, it is called either a subcooled liquid (the temper
21、ature is lower than the saturation temperature for the given pressure) or a compressed liquid (the pressure is greater than the saturation pressure for the given temperature).when a substance exists as part liquid and part vapor at the saturation temperature, its quality is defined as the ratio of t
22、he mass of vapor to the total mass. quality has meaning only when the substance is saturated (i.e., at saturation pressure and temperature).pressure and temperature of saturated substances are not independent properties.if a substance exists as a vapor at saturation temperature and pressure, it is c
23、alled a saturated vapor. (sometimes the term dry saturated vapor is used to emphasize that the quality is 100%.)when the vapor is at a temperature greater than the saturation temperature, it is a superheated vapor. pressure and temperature of a superheated vapor are independent properties, because t
24、he temperature can increase while pressure remains constant. gases such as air at room temperature and pressure are highly superheated vapors.first law of thermodynamicsthe first law of thermodynamics is often called the law of conservation of energy. the following form of the first-law equation is
25、valid only in the absence of a nuclear or chemical reaction.based on the first law or the law of conservation of energy for any system, open or closed, there is an energy balance asnet amount of energy net increase of stored=added to system energy in systemorenergy in energy out = increase of stored
26、 energy in systemfigure 1 illustrates energy flows into and out of a thermodynamic system. for the general case of multiple mass flows with uniform properties in and out of the system, the energy balance can be written (5)where subscripts i and f refer to the initial and final states,respectively.ne
27、arly all important engineering processes are commonly modeled as steady-flow processes. steady flow signifies that all quantities associated with the system do not vary with time. consequently, (6)where h = u + pv as described in equation (4).a second common application is the closed stationary syst
28、em for which the first law equation reduces to (7)second law of thermodynamicsthe second law of thermodynamics differentiates and quantifies processes that only proceed in a certain direction (irreversible) from those that are reversible. the second law may be described in several ways. one method u
29、ses the concept of entropy flow in an open system and the irreversibility associated with the process. the concept of irreversibility provides added insight into the operation of cycles. for example, the larger the irreversibility in a refrigeration cycle operating with a given refrigeration load be
30、tween two fixed temperature levels, the larger the amount of work required to operate the cycle. irreversibilities include pressure drops in lines andheat exchangers, heat transfer between fluids of different temperature, and mechanical friction. reducing total irreversibility in a cycle improves cy
31、cle performance. in the limit of no irreversibilities, a cycle attains its maximum ideal efficiency. in an open system, the second law of thermodynamics can be described in terms of entropy as (8)whereds = total change within system in time dt during process systemm s = entropy increase caused by ma
32、ss entering (incoming)m s = entropy decrease caused by mass leaving (exiting)q/t = entropy change caused by reversible heat transfer between system and surroundings at temperature tdi = entropy caused by irreversibilities (always positive)equation (8) accounts for all entropy changes in the system.
33、rearranged, this equation becomes (9)in integrated form, if inlet and outlet properties, mass flow, and interactions with the surroundings do not vary with time, the general equation for the second law is (10)in many applications, the process can be considered to operate steadily with no change in t
34、ime. the change in entropy of the system is therefore zero. the irreversibility rate, which is the rate of entropy production caused by irreversibilities in the process, can be determined by rearranging equation (10): (11)equation (6) can be used to replace the heat transfer quantity.note that the a
35、bsolute temperature of the surroundings with which the system is exchanging heat is used in the last term. if the temper-ature of the surroundings is equal to the system temperature, heat istransferred reversibly and the last term in equation (11) equals zero. equation (11) is commonly applied to a
36、system with one mass flow in, the same mass flow out, no work, and negligible kinetic or potential energy flows. combining equations (6) and (11) yields (12)in a cycle, the reduction of work produced by a power cycle (or the increase in work required by a refrigeration cycle) equals the absolute amb
37、ient temperature multiplied by the sum of irreversibilities in all processes in the cycle. thus, the difference in reversible and actual work for any refrigeration cycle, theoretical or real, operating under the same conditions, becomes (13)thermodynamic analysis ofrefrigeration cyclesrefrigeration
38、cycles transfer thermal energy from a region of low temperature t to one of higher temperature. usually the higher-tr temperature heat sink is the ambient air or cooling water, at temperature t0, the temperature of the surroundings.the first and second laws of thermodynamics can be applied to indivi
39、dual components to determine mass and energy balances and the irreversibility of the components. this procedure is illustrated in later sections in this chapter.performance of a refrigeration cycle is usually described by a coefficient of performance (cop), defined as the benefit of the cycle (amoun
40、t of heat removed) divided by the required energy input to operate the cycle:useful refrigerating effectcopuseful refrigeration effect/net energy supplied from external sources (14)net energy supplied from external sources for a mechanical vapor compression system, the net energy supplied is usually
41、 in the form of work, mechanical or electrical, and may include work to the compressor and fans or pumps. thus, (15)in an absorption refrigeration cycle, the net energy supplied is usually in the form of heat into the generator and work into the pumps and fans, or (16)in many cases, work supplied to
42、 an absorption system is very small compared to the amount of heat supplied to the generator, so the work term is often neglected.applying the second law to an entire refrigeration cycle shows that a completely reversible cycle operating under the same conditions has the maximum possible cop. depart
43、ure of the actual cycle from an ideal reversible cycle is given by the refrigerating efficiency: (17)the carnot cycle usually serves as the ideal reversible refrigeration cycle. for multistage cycles, each stage is described by a reversible cycle. equations of statethe equation of state of a pure su
44、bstance is a mathematical relation between pressure, specific volume, and temperature. when the system is in thermodynamic equilibrium,(18)the principles of statistical mechanics are used to (1) explore the fundamental properties of matter, (2) predict an equation of state based on the statistical n
45、ature of a particular system, or (3) propose a functional form for an equation of state with unknown parameters that are determined by measuring thermodynamic properties of a substance. a fundamental equation with this basis is the virial equation. the virial equation is expressed as an expansion in
46、 pressure p or in reciprocal values of volume per unit mass v as(19) (20)where coefficients b, c, d, etc., and b, c, d, etc., are the virial coefficients. b and b are second virial coefficients; c and c are third virial coefficients, etc. the virial coefficients are functions of temperature only, an
47、d values of the respective coefficients in equations (19) and (20) are related. for example, b = b/rt and c = (c b2)/(rt)2.the ideal gas constant r is defined as(21)where (pv)t is the product of the pressure and the volume along an isotherm, and tp is the defined temperature of the triple point of w
48、ater, which is 491.69r. the current best value of r is 1545.32 ft lbf/(lb moler).the quantity pv/rt is also called the compressibility factor; i.e.,z = pv/rt oran advantage of the virial form is that statistical mechanics can be used to predict the lower order coefficients and provide physical significance to the virial coefficients. for example, in equation(22), the term b/v is a function of interactions between two molecules, c/v2 between three molecules, etc. since the lower order interactions are common, the contributi
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